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A-Level Chemistry Revision

Kinetics & Equilibria

Reaction rates and rate equations, dynamic equilibrium, Kc and Kp, and acid-base equilibria.

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How does a catalyst speed up a reaction?

Kinetics & Equilibria is a core part of A-Level Chemistry. Revise the key concepts and common mistakes below, then lock them in with the free games.

Key concepts

Arrhenius eqnk = A e^(-Ea/RT).
Activation energy EaMinimum energy needed for reaction.
Pre-exp AFrequency factor; collisions of right geometry.
Boltzmann curveEnergy distribution of molecules at T.
CatalystLowers Ea; provides alt pathway.
ln k plotln k vs 1/T gives gradient -Ea/R.
Half-life t½Time for [A] to fall to half its value.
First-orderRate proportional to [A]^1; t½ constant.
Zero-orderRate independent of [A]; linear decay.
Second-orderRate proportional to [A]^2; t½ rises.
Concentration-timeGraph used to find order and k.
Integrated lawln[A] = ln[A0] - kt for 1st order.
RateChange in concentration per unit time.
Rate lawrate = k[A]^m[B]^n.

What your exam board covers

Where Kinetics & Equilibria sits in each exam board's specification. Tap a board to see what it lists.

AQAKineticsSpec 7405

Part of: Physical chemistry

Source: AQA A-level Chemistry (7405) specification — Subject content, accessed 23 June 2026.

EdexcelTopic 9: Kinetics ISpec 9CH0

Part of: Energetics, kinetics and equilibria

Source: Pearson Edexcel A-Level Chemistry (9CH0) specification, accessed 23 June 2026.

Eduqas/WJECPI5 — EquilibriaSpec A410QS (QAN 601/5645/4)
  • Equilibrium constants
  • Acid-base equilibria

Source: Eduqas/WJEC A-Level Chemistry specification (from 2015), accessed 24 June 2026.

Learn Kinetics & Equilibria step by step

Free interactive mini-lessons: short screens, worked examples and quick checks. Pick your exam board:

Other boards:CCEAOCR

Common mistakes to avoid

Questions where students often pick the tempting wrong answer — make sure you know the right one:

How does a catalyst speed up a reaction?✗ A catalyst lowers the activation energy of the original reaction pathway.   ✓ It provides an alternative reaction pathway with a lower activation energy.
Why does increasing temperature increase the rate of reaction significantly?✗ Particles collide much more frequently at higher temperature, which is the main reason for the rate increase.   ✓ Mainly because a much larger fraction of collisions have energy at least equal to the activation energy; collision frequency increases only slightly.
Can you determine the order of a reaction with respect to a reactant from the balanced equation?✗ The order of reaction with respect to each reactant equals its coefficient in the balanced equation.   ✓ No — orders must be determined experimentally; they often differ from the stoichiometric coefficients.
How does the rate of an SN2 reaction depend on concentrations?✗ SN2 reactions are first order overall because only the substrate matters.   ✓ Rate is first order in both substrate AND nucleophile (overall second order) because both are involved in the rate-determining step.
Increasing temperature increases the rate mainly because:✗ More collisions occur   ✓ A greater fraction of collisions exceed E_a

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