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CCEA GCSE Chemistry · Acids, Bases & Salts
Mini-Lesson

Acids, Bases & Salts

This mini-lesson walks you through the whole of the CCEA Acids, Bases & Salts unit: the pH scale and indicators, what makes a solution acidic or alkaline, neutralisation, the three reactions of acids, how to name a salt, and how to make soluble and insoluble salts.

acid H⁺(aq) + base OH⁻(aq) salt + water
The big idea: acid + base → salt + water.

Work through each screen, answer the questions as you go (some are wordy, some are calculations) and collect ⭐ stars. Press Start when you're ready.

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The pH scale

The pH scale measures how acidic or alkaline a solution is. It runs from 0 to 14.

  • pH less than 7 → acidic. The lower the pH, the more acidic.
  • pH exactly 7neutral (e.g. pure water).
  • pH greater than 7 → alkaline. The higher the pH, the more alkaline.
123 456 789 1011121314 ACIDIC NEUTRAL (7) ALKALINE Universal indicator: red ⟶ green ⟶ purple
The pH scale with universal indicator colours. Green is neutral, pH 7.
⚠️ Watch out: pH 7 is neutral, not "no pH". Pure water is pH 7. A pH of 6 is still slightly acidic — it does not have to be close to 0 to count as an acid.
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Indicators

Indicators change colour depending on the pH. CCEA expects you to know four:

Indicator In acid In alkali Litmus Methyl orange Phenolphthalein Universal ind. red red colourless red blue yellow pink purple
The four CCEA indicators and their colours in acid vs alkali.
  • Litmus: red in acid, blue in alkali.
  • Methyl orange: red in acid, yellow in alkali.
  • Phenolphthalein: colourless in acid, pink in alkali.
  • Universal indicator: a mixture of dyes giving a range of colours, so it tells you the actual pH — not just "acid or alkali".
Quick check

Read the indicator

?A few drops of phenolphthalein are added to a colourless solution and it turns pink. What can you conclude about the solution?
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What makes acids and alkalis

The behaviour comes down to the ions released in water:

  • An acid produces hydrogen ions, H⁺, when dissolved in water.
  • An alkali produces hydroxide ions, OH⁻, when dissolved in water. (An alkali is simply a soluble base.)

When an acid and an alkali react, the H⁺ and OH⁻ ions join to form water. This is neutralisation:

H⁺(aq) + OH⁻(aq) → H₂O(l)The same ionic equation describes every acid + alkali neutralisation.
💡 Bases vs alkalis: a base is any substance that neutralises an acid (often a metal oxide or hydroxide). An alkali is a base that dissolves in water, such as sodium hydroxide. All alkalis are bases; not all bases are alkalis.
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The three reactions of acids

CCEA expects you to know exactly what an acid makes with each of three reactants:

acid + metal → salt + hydrogene.g. 2HCl + Zn → ZnCl₂ + H₂  (metal must be above hydrogen in reactivity)
acid + base → salt + waterbase = metal oxide or hydroxide. e.g. H₂SO₄ + CuO → CuSO₄ + H₂O
acid + carbonate → salt + water + carbon dioxidee.g. 2HCl + CaCO₃ → CaCl₂ + H₂O + CO₂
⚠️ Watch out: only the carbonate reaction fizzes off CO₂; only the metal reaction gives off hydrogen. The base (oxide/hydroxide) reaction makes no gas — just salt and water. Test the CO₂ with limewater (turns milky); test hydrogen with a lit splint (squeaky pop).
Quick check

Name the products

?Dilute hydrochloric acid is added to calcium carbonate and the mixture fizzes. What are the products?
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Naming the salt

A salt's name has two parts. The first part comes from the metal (or ammonium) in the base/metal/carbonate. The second part comes from the acid:

Acid used Salt ending Hydrochloric acid (HCl) Sulfuric acid (H₂SO₄) Nitric acid (HNO₃) …chloride …sulfate …nitrate
The acid decides the ending: chloride, sulfate or nitrate.

So sodium hydroxide + nitric acid → sodium nitrate; copper oxide + sulfuric acid → copper sulfate; zinc + hydrochloric acid → zinc chloride.

⚠️ Watch out: the salt's ending always comes from the acid, never from the base. Hydrochloric → chloride, sulfuric → sulfate, nitric → nitrate.
Sort it

Acid + base → which salt?

Tap a reaction on the left, then tap the salt it makes on the right.

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Making a soluble salt (insoluble base method)

To make a soluble salt from an acid and an insoluble base, metal or carbonate, you use excess solid so all the acid reacts:

  • Add the solid (e.g. copper oxide) to warm acid until no more dissolves — the excess tells you all the acid is used up.
  • Filter off the leftover unreacted solid. The filtrate is the salt solution.
  • Evaporate some water, then leave to crystallise. Pat the crystals dry.
CuO + H₂SO₄ → CuSO₄ + H₂OCopper oxide (insoluble base) + sulfuric acid → copper sulfate crystals + water
💡 Why excess? Using excess insoluble solid guarantees the acid is fully neutralised, and the leftover solid simply gets filtered out — so the salt solution is left pure.
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Making a soluble salt (titration method)

When both the acid and the alkali are soluble (e.g. HCl + NaOH) you can't use excess solid — there is nothing to filter off. Instead use a titration:

burette: acid flask: alkali + indicator
Acid runs from the burette into a measured volume of alkali plus indicator.
  • Pipette a known volume of alkali into a flask with an indicator.
  • Run acid from the burette until the indicator just changes — the end-point, where the solution is neutral. Note the volume.
  • Repeat using the same volumes but no indicator, then evaporate and crystallise to get the pure salt.
Quick check

Pick the method

?You want pure crystals of sodium chloride from hydrochloric acid and sodium hydroxide (both soluble). Which preparation should you use?
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Insoluble salts by precipitation

If the salt you want is insoluble, you can't crystallise it from solution. Instead, mix two soluble solutions so the insoluble salt drops out as a solid — a precipitate:

silver nitrate + sodium chloride silver chloride ↓
Silver nitrate + sodium chloride → silver chloride (white precipitate) + sodium nitrate.

Then filter off the precipitate, wash it with distilled water and let it dry:

AgNO₃ + NaCl → AgCl↓ + NaNO₃Two soluble salts mixed; the insoluble AgCl precipitates out.
⚠️ Watch out: precipitation is the route for insoluble salts only. Don't try to make an insoluble salt by evaporating a solution, and don't try to make a soluble salt by precipitation.
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Solubility rules

You decide which method to use by knowing which salts are soluble. The CCEA rules:

  • All sodium, potassium and ammonium salts are soluble.
  • All nitrates are soluble.
  • Most chlorides are soluble — except silver chloride and lead chloride.
  • Most sulfates are soluble — except barium, lead and calcium sulfate.
  • Most carbonates and hydroxides are insoluble — except those of sodium, potassium and ammonium.
💡 Use it: want silver chloride (insoluble)? → precipitation. Want copper sulfate (soluble)? → acid + insoluble base, filter, crystallise.
Sort it

Soluble or insoluble?

Tap a salt, then tap the box it belongs in. Use the solubility rules.

💧 Soluble

🧱 Insoluble

Learn it · Higher tier

Strong vs weak acids (Higher)

Strength is about how fully an acid ionises (splits into ions) in water — it is not the same as concentration:

  • A strong acid (e.g. hydrochloric, sulfuric, nitric) is fully ionised — almost every molecule releases its H⁺. This gives a high H⁺ concentration and a low pH.
  • A weak acid (e.g. ethanoic acid, carbonic acid) only partially ionises — most molecules stay whole. Fewer H⁺ ions, so a higher pH for the same concentration.
Strong: fully ionised H⁺H⁺H⁺H⁺H⁺ Weak: partly ionised HAHAH⁺HA
Same concentration, different ionisation: the strong acid releases far more H⁺.
⚠️ Watch out: strong ≠ concentrated. A dilute strong acid can have more free H⁺ than a concentrated weak acid. Strength = degree of ionisation; concentration = how much acid per volume.
Quick check · Higher tier

Strong or weak? (Higher)

?Why does ethanoic acid have a higher pH than hydrochloric acid of the same concentration?
Recap

Pull it together

pH & indicators: 0–14, 7 = neutral; litmus (red/blue), methyl orange (red/yellow), phenolphthalein (colourless/pink), universal indicator (range).

Ions: acids give H⁺, alkalis give OH⁻; neutralisation is H⁺ + OH⁻ → H₂O.

Reactions of acids: + metal → salt + hydrogen; + base → salt + water; + carbonate → salt + water + CO₂.

Naming: ending from the acid — chloride / sulfate / nitrate.

Making salts: soluble → excess insoluble solid then filter & crystallise, or titration for acid + alkali; insoluble → precipitation (mix, filter, wash, dry).

Higher: strong acids fully ionise (low pH); weak acids partially ionise — strength ≠ concentration.

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