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Cambridge IGCSE Chemistry (0620) · Topic 8 — The Periodic Table
Mini-Lesson

The Periodic Table

This mini-lesson walks you through the whole of Cambridge IGCSE Chemistry (0620) Topic 8: how the table is arranged, the Group I alkali metals, the Group VII halogens, the transition elements and the noble gases.

groups (columns) periods (rows) increasing proton (atomic) number

Work through each screen, answer the questions as you go and collect ⭐ stars. Supplement (extended-only) points are clearly flagged. Press Start when you're ready.

8.1 · Arrangement

How the table is built

The elements are laid out in order of increasing proton number (atomic number) — each element has one more proton than the one before it. Two rules let you read off an atom's electron arrangement straight from its position:

  • The group number (the vertical column, I–VIII) tells you the number of electrons in the outer shell.
  • The period number (the horizontal row, 1–7) tells you the number of occupied electron shells.
III IIIIVVVIVII 0 23 Li Be Na Mg B C N O F Al Si P S Cl metals (left) non-metals (right) Group number = outer-shell electrons · Period number = occupied shells.
Metals sit on the left, non-metals on the right. Na is in Group I, Period 31 outer electron, 3 shells.
⬥ Supplement (extended only)
You can predict properties of an element from its position. Across a period, elements change from metallic to non-metallic character (left to right).
Quick check

Reading a position

?An element sits in Group II, Period 3. How many electrons are in its outer shell, and how many occupied shells does it have?
8.2 · Group I — the alkali metals

The alkali metals

Lithium, sodium and potassium are the alkali metals you must know. Their physical properties stand out for metals:

  • Soft — they can be cut with a knife.
  • Low density — Li, Na and K all float on water.
  • Low melting points (low for metals).

They react with water to give a metal hydroxide (an alkaline solution) plus hydrogen gas:

2Na + 2H₂O → 2NaOH + H₂sodium + water → sodium hydroxide + hydrogen
down the group Lithium gentle fizzing on water Sodium whizzes about, melts into a ball Potassium ignites, lilac flame — most reactive reactivity INCREASES ↓
Reactivity with water increases down Group I: K reacts far more violently than Li.

Watch out: Group I reactivity increases down the group. This is the opposite of Group VII (the halogens), where reactivity decreases down the group — a classic exam trap.

⬥ Supplement (extended only)
The trend is explained by the single outer electron: further down the group the outer electron is in a shell further from the nucleus, so it is held less tightly and is lost more easily — making the atom more reactive.
Quick check

Predict the Group I trend

?Rubidium (Rb) sits below potassium in Group I. Predict how it reacts with water compared with potassium.
8.3 · Group VII — the halogens

The halogens

The halogens are coloured, diatomic non-metals. Their colours and physical states at room temperature are worth memorising:

down the group Chlorine Cl₂ pale yellow-green GAS Bromine Br₂ red-brown LIQUID Iodine I₂ grey-black SOLID reactivity DECREASES ↓ colour gets DARKER ↓ m.p. & density RISE ↓ gas → liquid → solid going down
Going down: chlorine (gas) → bromine (liquid) → iodine (solid). Colour darkens, melting point and density rise, reactivity falls.

A more reactive halogen will displace a less reactive halogen from a solution of its salt (a halide). For example, chlorine displaces bromine:

Cl₂ + 2KBr → 2KCl + Br₂chlorine + potassium bromide → potassium chloride + bromine
Cl₂ added to KBr (colourless) more reactive Cl displaces less reactive Br solution turns orange (Br₂ formed) Iodine cannot displace bromine — it is less reactive.
Displacement: the more reactive halogen ends up as the element; the displaced halogen's colour appears in solution.

Watch out: displacement only happens when the added halogen is more reactive than the one in the salt. Chlorine displaces bromine and iodine; bromine displaces only iodine; iodine displaces neither.

⬥ Supplement (extended only)
Reactivity decreases down Group VII because a halogen reacts by gaining one electron. Lower down, the outer shell is further from the nucleus, so the atom attracts and gains an electron less easily.
Match-up

Halogen colours & states

Tap a halogen on the left, then tap its correct colour and state on the right.

Quick check

Will it displace?

?Bromine water is added to a colourless solution of potassium iodide (KI). What happens?
Quick check

Identify the halogen

?A Group VII element is a red-brown liquid at room temperature. Which halogen is it?
8.4 · The transition elements

The transition elements

The transition elements sit in the central block of the table (between Groups II and III). Compared with the Group I metals, they are typically:

I II TRANSITION ELEMENTS III – VIII 🏋️ high density 🔥 high melting points 🎨 form coloured compounds ⚙️ act as catalysts 🔁 variable oxidation numbers ⬥ vs Group I metals: those are soft, low-density, low-m.p., white compounds, fixed +1 charge.
Coloured compounds (e.g. blue Cu²⁺, green Fe²⁺, orange Fe³⁺) and catalysis (e.g. iron in the Haber process) are hallmark transition-metal behaviour.

Watch out: don't confuse transition metals with Group I. Group I metals are soft, low-density with low melting points and form white/colourless compounds; transition metals are hard, dense with high melting points and coloured compounds.

⬥ Supplement (extended only)
Transition elements have ions with variable oxidation numbers (variable charges) — for example iron forms Fe²⁺ (iron(II)) and Fe³⁺ (iron(III)). Group I metals only ever form a fixed +1 ion.
Quick check

Transition or Group I?

?Which property is typical of a transition element but not of a Group I metal?
8.5 · The noble gases (Group VIII / 0)

The noble gases

The noble gases — helium, neon, argon and the rest — form Group VIII (also written Group 0). They are unreactive (inert) and exist as single atoms (monatomic gases).

Ar full outer shell (8 electrons) Uses 💡 argon — filling lamps / inert shield 🎈 helium — balloons & airships (low density) 🔆 neon — bright advertising lights
A full outer shell means a noble gas has no tendency to gain, lose or share electrons — so it stays inert.

Why so unreactive? Noble gases already have a full outer electron shell. They have no need to gain, lose or share electrons, so they hardly react with anything. This stable arrangement is exactly what other elements react to achieve.

Quick check

Why are they unreactive?

?The noble gases are extremely unreactive. What is the reason?
Sort it

Which way does reactivity go?

Tap a statement, then tap the box that matches the trend going down the group.

⬆ Reactivity INCREASES down

⬇ Reactivity DECREASES down

Recap

The points to know

Arrangement: increasing proton number; group number = outer electrons; period number = occupied shells. ⬥ predict properties; metallic → non-metallic across a period.

Group I: soft, low density, low m.p.; react with water → hydroxide + hydrogen; reactivity increases down. ⬥ outer electron lost more easily lower down.

Group VII: Cl₂ pale yellow-green gas, Br₂ red-brown liquid, I₂ grey-black solid; reactivity decreases down; more reactive halogen displaces less reactive. ⬥ harder to gain an electron lower down.

Transition elements: high density, high m.p., coloured compounds, catalysts. ⬥ variable oxidation numbers (Fe²⁺/Fe³⁺).

Noble gases (VIII/0): unreactive, monatomic, full outer shells; uses (argon, helium, neon).

You've covered all of Cambridge IGCSE Chemistry (0620) Topic 8 — The Periodic Table. Press Finish to see your score.

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