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Cambridge IGCSE Chemistry (0620) · Topic 1 — States of matter
Mini-Lesson

States of Matter

This mini-lesson walks you through the whole of Cambridge IGCSE Chemistry Topic 1: the three states and their properties, the kinetic particle model, the changes of state and heating curves, how temperature and pressure affect a gas, and diffusion.

solid liquid gas same particles — different arrangement, spacing and motion

Work through each screen, answer the questions as you go (some are wordy, some are calculations) and collect ⭐ stars. Items marked SUPPLEMENT are extended-only. Press Start when you're ready.

1.1 · the three states

Solids, liquids and gases

Matter exists in three states. Cambridge expects you to state the distinguishing properties of each:

  • Solid — fixed shape and fixed volume; cannot be compressed (squashed).
  • Liquid — fixed volume but takes the shape of its container; cannot be compressed; can flow.
  • Gas — no fixed shape and no fixed volume; fills its container; can be compressed; can flow.

Watch out: both liquids and gases can flow, so we call them fluids. The big differences are that a gas has no fixed volume and is easily compressed, while a liquid is not.

1.1 · the kinetic particle model

Particles in each state

Describe each state in terms of particle separation, arrangement and motion:

solid close · regular rows · vibrate in place liquid close · random · slide past each other gas far apart · random · fast in all directions
From solid → gas the particles get further apart, more disordered and faster-moving (more energy).

Common mistake: heating does not make the particles themselves get bigger. The particles stay the same size — they gain energy, move more, and the spacing between them changes.

Quick check

Read the particle diagram

?The particles above are close together but irregularly arranged, and they can slide past one another. Which state of matter is shown?
Sort it

Which state?

Tap the state that best matches each particle description.

1.1 · changes of state

Changing state

Adding or removing energy moves a substance between states. Cambridge names five changes you must describe:

SOLID LIQUID GAS melting freezing boiling / evaporating condensing
Melting & boiling/evaporating need energy in; freezing & condensing release energy.
  • Melting — solid → liquid (at the melting point).
  • Boiling — liquid → gas, throughout the liquid, at the boiling point.
  • Evaporating — liquid → gas from the surface only, below the boiling point.
  • Freezing — liquid → solid.
  • Condensing — gas → liquid.

Conservation of mass: changes of state are physical changes — no new substance forms and mass is conserved. Sealed ice that melts then boils has the same mass throughout; only the arrangement and energy of the particles change.

Extension note: a few solids (e.g. solid carbon dioxide, iodine) turn straight to gas — sublimation. This is useful background, but the named changes assessed in 0620 Topic 1 are the five above.

Quick check

Name the change

?Steam from a kettle hits a cold window and turns into droplets of liquid water on the glass. What is this change of state called?
1.1 · Supplement SUPPLEMENT

Heating curves & the energy story

Extended only. Explain changes of state using kinetic particle theory. As you heat a solid steadily, a heating curve (temperature against time) shows two flat plateaus:

temperature → time / energy supplied → m.p. b.p. solid melting liquid boiling gas
The temperature is constant on each plateau because the energy supplied is overcoming forces between particles (changing state), not raising their average kinetic energy.
  • Rising sections: energy increases the particles' average kinetic energy, so the temperature rises.
  • Lower plateau (melting): energy goes into weakening/overcoming forces holding the solid together — temperature stays at the melting point.
  • Upper plateau (boiling): energy separates particles completely into a gas — temperature stays at the boiling point.

Cooling curve: run it in reverse. Plateaus appear at the freezing point (gas→liquid→solid) as particles release energy while staying at the same temperature.

Quick check SUPPLEMENT

Reading the heating curve

?On a heating curve the temperature stays constant along the lower flat plateau. What is happening to the energy being supplied here?
1.1 · gases under change

Temperature, pressure & a gas

Cambridge expects you to describe the effects of temperature and pressure on the volume of a gas (qualitatively):

  • Higher temperature (pressure fixed): particles gain energy and move faster, so the gas expands — its volume increases.
  • Higher pressure (temperature fixed): the gas is squeezed into a smaller space, so its volume decreases.
cool gas heat expanded gas low pressure squeeze
Heating spreads a gas out (bigger volume); raising the pressure squeezes it (smaller volume).

Supplement explanation SUPPLEMENT: in terms of kinetic particle theory, gas pressure comes from particles colliding with the walls. Heating makes them move faster and hit the walls harder and more often; if the container can expand, the gas takes up more room. Pushing the walls in (more pressure) packs the particles closer, so the volume falls.

Quick check

What happens to the gas?

?A sealed balloon is left in bright sunshine and warms up. The pressure stays about the same. What happens to the volume of the gas inside?
1.2 · diffusion

Diffusion — evidence for moving particles

Diffusion is the spreading out of particles from a region of higher concentration to a region of lower concentration, until they are evenly mixed.

drop added time spreading evenly mixed
Diffusion is evidence that particles are moving — they spread by themselves with no stirring.

Explain it with kinetic particle theory: particles are in constant random motion. They move from where there are more of them to where there are fewer, mixing without being stirred. Diffusion is fastest in gases (particles far apart, moving fast), slower in liquids, and negligible in solids.

Why it matters: smelling perfume across a room is diffusion — the smell particles move and spread through the air all on their own.

1.2 · Supplement SUPPLEMENT

Diffusion rate & molecular mass

Extended only. The rate of diffusion of a gas depends on its relative molecular mass (Mr): lighter molecules diffuse faster than heavier ones at the same temperature.

NH₃ Mr = 17 (light, fast) HCl Mr = 36.5 (heavy, slow) white ring (NH₄Cl) centre
The white ring of ammonium chloride forms nearer the HCl end — the lighter NH₃ (Mr 17) travelled further and faster than the heavier HCl (Mr 36.5).

In the classic experiment, cotton wool soaked in ammonia solution (giving NH₃ gas) and concentrated hydrochloric acid (giving HCl gas) are put at opposite ends of a glass tube. Where the gases meet, a white ring of ammonium chloride (NH₄Cl) forms — and it forms closer to the HCl end.

Reasoning SUPPLEMENT: at the same temperature the gas particles have the same average kinetic energy, so the lighter NH₃ molecules move faster and cover more of the tube before meeting the slower, heavier HCl molecules.

Predict it SUPPLEMENT

Which gas wins the race?

?Hydrogen gas (H₂, Mr = 2) and carbon dioxide (CO₂, Mr = 44) are released at opposite ends of a long tube at the same temperature. Which statement is correct?
Recap

Topic 1 at a glance

Three states: solid (fixed shape & volume), liquid (fixed volume, takes shape), gas (no fixed shape or volume, compressible).

Particle model: spacing, arrangement & motion increase solid → liquid → gas; particles don't change size, the spacing/energy does.

Changes of state: melting, boiling, evaporating, freezing, condensing — physical changes; mass conserved.

Heating curves SUPP: plateaus at m.p. & b.p. — energy overcomes forces, not raising temperature.

Gas volume: ↑ temperature → expands; ↑ pressure → smaller volume.

Diffusion: particles spread high → low concentration; SUPP lighter molecules diffuse faster (NH₃ vs HCl).

You've covered the whole of Cambridge IGCSE Chemistry (0620) Topic 1 — States of matter, with the Supplement (extended) items flagged. Press Finish to see your score.

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