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IB Diploma Physics SL · Theme B.3 Gas laws
Mini-Lesson

Gas Laws & Kinetic Theory

This mini-lesson covers Theme B.3 — Gas laws: the ideal gas equation pV = nRT, the experimental gas laws (Boyle, Charles, pressure law), and the kinetic theory that explains them from molecular motion.

pV = nRT Boyle · Charles kinetic theory

Work through each screen, answer the questions as you go (some are reasoning, some are calculations) and collect ⭐ stars. Watch for the HL flag on higher-level extensions. Press Start when you're ready.

B.3 · ideal gas

The ideal gas equation

An ideal gas obeys the equation of state linking pressure, volume, amount and temperature:

pV = nRTp (Pa) · V (m³) · n (mol) · R = 8.31 J mol⁻¹ K⁻¹ · T (K, always!)

Temperature must be in kelvin in every gas calculation. The number of moles n = N ÷ N_A, where N is the number of molecules and N_A = 6.02 × 10²³ mol⁻¹.

Quick check

Quick check

?A sealed rigid container of ideal gas is heated. Which of these must you convert before using pV = nRT?
Calculate

Calculate

#Find the amount of gas (in mol) when p = 1.0 × 10⁵ Pa, V = 0.024 m³ and T = 290 K. Use R = 8.31.
mol
Hint: n = pV ÷ (RT) = (1.0e5 × 0.024) ÷ (8.31 × 290).
B.3 · gas laws

Boyle's and Charles's laws

Holding one quantity fixed gives the experimental gas laws:

  • Boyle's law (constant T): p ∝ 1/V, so p₁V₁ = p₂V₂.
  • Charles's law (constant p): V ∝ T, so V₁/T₁ = V₂/T₂.
  • Pressure law (constant V): p ∝ T, so p₁/T₁ = p₂/T₂.
Worked example — Boyle's law

Gas at 100 kPa fills 2.0 L. Compress it to 0.50 L at constant temperature.

p₂ = p₁V₁ ÷ V₂ = 100 × 2.0 ÷ 0.50 = 400 kPa

Calculate

Calculate

#A gas at 100 kPa occupies 2.0 L. It is compressed at constant temperature to 0.50 L. Find the new pressure (kPa).
kPa
Hint: Boyle — p₂ = p₁V₁ ÷ V₂ = 100 × 2.0 ÷ 0.50.
Calculate

Calculate

#A gas occupies 0.30 m³ at 300 K. It is heated at constant pressure to 400 K. Find the new volume (m³).
Hint: Charles — V₂ = V₁ × T₂ ÷ T₁ = 0.30 × 400 ÷ 300.
Sort it

Which gas law is being used?

Tap an item, then tap the group it belongs to.

🔒 Boyle (const T)

🌡️ Charles (const p)

📦 Pressure law (const V)

B.3 · kinetic theory

Kinetic theory of gases

Kinetic theory models a gas as many tiny molecules in random motion. Pressure arises from countless collisions with the walls. The model assumes point molecules, no intermolecular forces, and perfectly elastic collisions.

average KE = (3/2)kTk = 1.38 × 10⁻²³ J K⁻¹ (Boltzmann constant); KE ∝ absolute temperature

This links the microscopic and macroscopic: the average translational kinetic energy of a molecule depends only on the absolute temperature — not on the type of gas.

Calculate

Calculate

#Find the average translational kinetic energy of a molecule at 300 K, in units of 10⁻²¹ J. Use k = 1.38 × 10⁻²³ J K⁻¹.
× 10⁻²¹ J
Hint: KE = (3/2)kT = 1.5 × 1.38e-23 × 300 = 6.21e-21 J → 6.21.
Match it

Match the statement to its name

Tap a statement on the left, then its match on the right.

Statement
Answer
Recap

The big ideas to know

Ideal gas: pV = nRT; T always in kelvin; n = N ÷ N_A

Boyle: constant T: p₁V₁ = p₂V₂

Charles / pressure law: V ∝ T (const p) · p ∝ T (const V)

Kinetic theory: pressure from wall collisions; average KE = (3/2)kT

Key idea: average molecular KE depends only on absolute temperature

That completes Gas Laws & Kinetic Theory for IB Diploma Physics SL. Press Finish to see your score.

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