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IB Diploma Chemistry HL · Structure 3.1 — the periodic table and periodicity
Mini-Lesson

The periodic table and periodicity

This mini-lesson covers Structure 3.1: how the periodic table is organised and the periodic trends in atomic radius, ionisation energy, electronegativity and reactivity. This HL lesson also builds in the Additional Higher Level (AHL) material.

the tableacross a perioddown a group Structure 3.1 — the periodic table and periodicity

Work through each screen, answer the questions as you go (some are wordy, some are calculations) and collect ⭐ stars. Press Start when you're ready.

Structure 3.1

How the table is built

Elements are arranged by increasing atomic number.

  • A period (row) = the highest occupied energy level (shell).
  • A group (column) = the number of valence (outer) electrons, and hence similar chemistry.
  • Blocks: s, p and d follow the sub-level being filled.

So an element's position tells you its electron configuration, and vice versa.

Calculate

Find the group

1An atom has the electron arrangement 2, 8, 7. Which group of the periodic table is it in?
The group number matches the valence electrons; here 7 outer electrons → group 17 (the halogens).
Calculate

Find the period

2For the same atom (2, 8, 7), which period is it in?
The period equals the number of occupied shells; here there are three shells → period 3 (chlorine).
Structure 3.1

Atomic radius

Across a period the radius decreases: the nuclear charge rises but electrons enter the same shell, so the stronger pull draws them in.

Down a group the radius increases: each element adds a full shell, so outer electrons are further out and shielded.

Structure 3.1

Ionisation energy

The first ionisation energy is the energy to remove one mole of electrons from one mole of gaseous atoms.

  • Across a period: increases (greater nuclear charge, smaller radius).
  • Down a group: decreases (electrons further out and more shielded).

The pattern of ionisation energies is direct evidence for electron shells.

Quick check

Ionisation-energy trend

?Why does first ionisation energy generally increase across a period?
Structure 3.1

Electronegativity and character

Electronegativity increases across a period and decreases down a group, peaking near fluorine.

So metallic character decreases across a period (metals on the left, non-metals on the right) and increases down a group. Metal oxides tend to be basic; non-metal oxides tend to be acidic.

Structure 3.1

Group trends in reactivity

Group 1 (alkali metals): reactivity increases down the group — the outer electron is lost more easily.

Group 17 (halogens): reactivity decreases down the group — it is harder to gain an electron as atoms get bigger.

Quick check

Alkali metals

?Which alkali metal is the MOST reactive?
AHL — Structure 3.1

First-row transition elements

Transition elements have partly filled d sub-shells, giving variable oxidation states, coloured compounds (from d–d electron transitions) and useful catalytic behaviour. They also form complex ions with ligands.

AHL check

Why coloured?

?Transition-metal complexes are often coloured because:
AHL calculate

Variable oxidation state

HWhat is the oxidation state of iron in Fe₂O₃?
2x + 3(−2) = 0, so 2x = +6, x = +3.
Sort it

Which way does it trend?

Tap a trend, then how it changes.

⬆️ Increases across a period

⬇️ Decreases across a period

🔽 Increases down a group

Match it

Match the pattern

Tap an item on the left, then its match on the right.

Feature
Trend
Recap

The big ideas to know

Layout: period = number of shells; group = valence electrons; s/p/d blocks

Across a period: radius ↓, ionisation energy ↑, electronegativity ↑

Down a group: radius ↑, ionisation energy ↓

Reactivity: group 1 ↑ down; group 17 ↓ down; metal oxides basic, non-metal oxides acidic

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